Composite oxides comprising strontium, lantanium, yttrium and ionic conductors using the same

ABSTRACT

Disclosed is a novel strontium-lanthanum-yttrium-containing metal composite oxide. An ionic conductor comprising the metal composite oxide and an electrochemical device comprising the ionic conductor are also disclosed. The metal composite oxide has an improved ionic conductivity, because formation of an open space within a lattice is ensured by the defects of metal ion sites in the lattice. Therefore, the metal composite oxide is useful for an ionic conductor or an electrochemical device requiring ionic conductivity.

This application claims the benefit of the filing date of Korean PatentApplication No. 2005-97716, filed on Oct. 17, 2005, in the KoreanIntellectual Property Office, the disclosure of which is incorporatedherein in its entirety by reference.

TECHNICAL FIELD

The present invention relates to a novel metal composite oxide thatexhibits ionic conductivity. More particularly, the present inventionrelates to a strontium-lanthanum-yttrium-containing metal compositeoxide with an open space formed for easy movement and transfer of ionsdue to metal ion defects in a crystal lattice, an ionic conductorcomprising the novel metal composite oxide and an electrochemical devicecomprising the ionic conductor.

BACKGROUND ART

Active studies have been carried out to ionic conductors, particularlyoxygen ion conductors, which are electrolytes used in electrochemicaldevices, such as gas sensors and fuel cells.

Currently, in solid oxide fuel cell (“SOFC”) applications, it is knownthat yttrium stabilized zirconia (“YSZ”) is the most suitable materialfor use as a high-temperature SOFC electrolyte. However, a dopedceria-type is more suitable for a low-temperature (lower than 600° C.)SOFC. In a high-temperature SOFC using any other electrolyte (dopedceria or La_(0.8)Sr_(0.2)GaO_(3−δ)) than YSZ, materials such asLa_(0.9)Sr_(0.1)AlO_(3−δ) or Gd₂Zr₂O₇ can be used as a protective layerof a cathode. An ionic conductor membrane for use in an oxygen pumpshould have both electrical conductivity and ionic conductivity.Accordingly, doped ceria, rather than YSZ with very low electricalconductivity, is suitable for being used in an oxygen pump.

Although all the materials as described above have a certain potentialin industrial applications, they have merits and demerits depending onparticular application to which they are applied. It is thought thatthis is because each material shows different ionic conductivitycharacteristics and physicochemical properties depending on temperaturesdue to its unique feature such as crystalline structure or ion defectstructure. Therefore, it is very important to develop new materialshaving various ionic conductivity characteristics required for variousapplications. Such materials may result in the rapid development ofrelevant technologies requiring ion conductors.

BRIEF DESCRIPTION OF THE DRAWINGS

The foregoing and other objects, features and advantages of the presentinvention will become more apparent from the following detaileddescription when taken in conjunction with the accompanying drawings inwhich:

FIG. 1 is a graph showing the X-ray diffraction (XRD) patterns of thestrontium-lanthanum-yttrium-containing metal composite oxides preparedin Examples 1˜7;

FIG. 2 is a Rietveld profile illustrating the XRD pattern of thestrontium-lanthanum-yttrium-containing metal composite oxide(Sr₅La₆Ta₄O₂₁) prepared in Example 1 when compared with the theoreticalpattern of a structure model;

FIG. 3 is a lattice structure view of thestrontium-lanthanum-yttrium-containing metal composite oxide(Sr₅La₆Ta₄O₂₁) prepared in Example 1; and

FIG. 4 is a graph showing ionic conductivity of thestrontium-lanthanum-yttrium-containing metal composite oxides preparedin Examples 1˜7 as a function of temperature.

DISCLOSURE OF THE INVENTION

The inventors have discovered that a novel metal composite oxideessentially comprising strontium (Sr), lanthanum (La) and yttrium (Y)mixed with at least one different chemical species has specific metalion defects that have not been known to date and shows an improved ionicconductivity by ensuring the formation of an open space within a crystallattice by the metal ion defects.

Therefore, it is an object of the present invention to provide a novelmetal composite oxide having ionic conductivity, an ionic conductorcomprising the metal composite oxide, and an electrochemical devicecomprising the ionic conductor.

The present invention provides a novel metal composite oxide representedby the following Formula 1, an ionic conductor comprising the metalcomposite oxide, and an electrochemical device comprising the ionicconductor:

[Formula 1]Sr_(5+x+y)La_(6−x−2y)Y_(y)B₄O_(24−δ)C_(z)  (I)

wherein B is at least one element selected from the group consisting ofTa and Nb;

C is at least one anion selected from the group consisting of S andhalogen atoms, or H⁺ cation;

x is a decimal ranging from −1 to 1 (−1≦x≦1);

y is a decimal ranging from 0 to 2.5 (0≦y≦2.5);

δ is a decimal ranging from 0 to 3 (0≦δ≦3); and

z is a decimal ranging from 0 to 7 (0≦z≦7).

Also, the present invention provides an ionic conductor, which hasordered metal defects in a lattice structure of perovskite-like √{squareroot over (2)}×√{square root over (2)}×4 super structure.

Hereinafter, the present invention will be explained in more detail.

The novel metal composite oxide according to the present invention ischaracterized by having improved ionic conductivity due to the presenceof unique metal ion defects in a lattice.

The novel metal composite oxide according to the present invention hasordered metal defects in specific metal sites in a lattice structure.Herein, the metal defects are not conventional defects that are randomlypositioned and disordered in a lattice structure, but ordered inspecific sites. Such metal defects can ensure formation of an additionalopen space in a lattice structure, and the open space facilitates ionmovements, so as to impart improved ionic conductivity. Hence, the novelmetal composite oxide according to the present invention may be expectedto serve sufficiently as an ionic conductor showing conductivityaccording to the ion movement and transfer.

In fact, as can be seen from the following experimental examples, themetal composite oxide according to the present invention, represented bythe above Formula 1, includes specific metal ion defects and has a highoxygen ionic conductivity (see Table 2 and FIGS. 3 and 4).

In addition, according to another feature of the present invention, thecompound represented by Formula 1 can provide diverse ionic conductivitycharacteristics, without any significant change in crystal structure,merely by slightly modifying the composition of chemical species formingthe compound. This indicates that when two or more kinds of materialshaving different electrical conductivities are required to be bondedwith each other in solid oxide fuel cell or gas sensor applications, themetal composite oxide represented by Formula 1 may be suitably appliedthereto merely by modifying the chemical composition of the metalcomposite oxide without any significant change in crystal structure soas to adopt materials having diverse ionic conductivity characteristics.Therefore, the present invention may result in the rapid development ofrelevant technologies requiring ionic conductivity.

The novel metal composite oxide according to the present invention isrepresented by the above Formula 1.

The metal composite oxides represented by Formula 1 is a novel compositeoxide that has never been disclosed to date, while it includes metal iondefects ordered in the lattice structure. Therefore, the metal compositeoxide ensures formation of an open space within the lattice due to thepresence of the metal defects, thereby showing excellent ionicconductivity.

Preferably, the metal ion defects have crystallographic coordinates of4a position (x=0, y=0.25, z=0.125) after a proper lattice translation ifneeded and a site occupancy of 0˜1, but are not limited thereto. Herein,the crystallographic coordinates in the lattice are based on space groupNo. 88, origin choice 2, described in p. 361 of “International tablesfor crystallography” (vol. A, 5^(th) ed. Kluwer Academic Publishers,2002).

In the metal composite oxide represented by Formula 1, C is preferablyan H⁺ cation (proton). This is because H⁺ (proton) present in thelattice due to the absorption of moisture (H₂O) included in a wetatmosphere can easily move through the open space formed by the metalion defects, as mentioned above, and function as an ionic conductor.

In practice, it is known that many perovskite-like oxides having oxygenionic conductivity generally show hydrogen ionic conductivity in amoisture-containing atmosphere (T. Norby, Solid State Ionics, 125 (1999)1-11; I. Animitsa, T. Norby, S. Marion, R. Glockner, A. Neiman, SolidState Ionics, 145, (2001) 357-364). In view of this fact, it is assumedthat the metal composite oxide according to the present invention, whichincludes specific metal ion defects and show oxygen ionic conductivitythrough an open space formed by such metal ion defects, may also allowhydrogen ions (protons) to easily move through the open space, and thusexhibit both oxygen ionic conductivity and hydrogen ionic conductivity.

The metal composite oxide represented by Formula 1 may have a crystalstructure of the perovskite structure or perovskite-like 2√{square rootover (2)}×2√{square root over (2)}×4 super structure. Also, the metalcomposite oxide may have a tetragonal crystal system, whose space groupis I4₁/a (space group No. 88), and the crystal system may have thefollowing lattice parameters: a=11.661±0.5 Å and c=16.577±0.5 Å.However, the scope of the present invention is not limited thereto.

Non-limiting examples of the metal composite oxide represented byFormula 1 include Sr₅La₆Ta₄O₂₄, Sr_(5.5)La_(4.5)Y₁Ta₄O_(23.75),Sr₆La₄Y₁Ta₄O_(23.5), Sr₇La_(1.5)Y_(2.5)Ta₄O₂₃, Sr₇La₂Y₂Ta₄O₂₃,Sr₇La₃Y₂Ta₄O₂₃, Sr_(7.5)La_(1.5)Y₂Ta₄O_(22.75), or the like.

Besides the compound represented by Formula 1 or derivatives thereof,any compounds having the aforementioned structural features and showingionic conductivity may also be included in the scope of the presentinvention. For example, the metal composite oxide prepared by using Nbelement instead of Ta, includes metal ion defects ordered in the latticestructure, thereby shows excellent ionic conductivity.

The metal composite oxide according to the present invention can beprepared by conventional methods generally known to those skilled in theart. For example, the metal composite oxide can be prepared by mixingprecursor compounds each containing one or more elements specified inFormula 1 (e.g. (a) Sr, La, Y or a combination thereof; and (b) Ta, Nbor a combination thereof, or the like), at an appropriate molar ratio,calcining the resultant mixture at a temperature between 700° C. and1,700° C., and then cooling the mixture.

As the precursor compounds of the metal composite oxide of Formula 1,any salts containing one or more elements selected from the groupconsisting of (a) Sr, La and Y; and (b) Ta, Nb, etc. can be used. Thereis no limitation in the molar ratio of the precursor compounds. Theprecursor compounds can be mixed together at an appropriate molar ratiodetermined according to the final product.

Preferably, the mixture of the precursor compounds is calcined at atemperature above 700° C., preferably between 700° C. and 1,700° C., for5 to 72 hours.

For the calcination process, the following conventional methods can beused: a first method of forming the mixture in a pellet and calciningthe pellet; and a second method of calcining the mixture itself.However, there is no limitation in using any calcination method.

The calcined mixture is cooled to room temperature to obtain asingle-phase metal composite oxide having the novel crystal structureaccording to the present invention (for example, astrontium-lanthanum-yttrium-niobium (or tantalum) oxide and derivativesthereof). The cooling process can be carried out at room temperature.Alternatively, the calcined mixture can be rapidly cooled by usingliquid nitrogen or water at room temperature.

The present invention provides ionic conductors including metalcomposite oxides with the novel crystal structure, preferably, oxygen-or proton-selective ionic conductors.

Ionic conductors are materials that conduct electricity with themovement of ions. Generally, ionic conductors are used in the form of amembrane having a separating factor through which one elementselectively permeates.

The ionic conductors according to the present invention can be preparedby using a conventional method generally known in the art. For example,the ionic conductor can be prepared by coating a conductive electrode toapply an electric field. At this time, a metal composite oxide of thepresent invention can be used alone as an ionic conductor or mixedappropriately with any other materials known in the art according topurposes or applications.

In addition, the present invention provides electrochemical devicescomprising metal composite oxides having the novel crystal structure asionic conductors.

The electrochemical devices can be any device for performingelectrochemical reactions, which includes, but is not limited to, anoxygen probe, a fuel cell, a chemical membrane reactor, an oxygenseparation membrane, an oxygen pump, a hydrogen separation membrane, ahydrogen pump, a hydrogen gas sensor, a steam sensor, a hydrocarbonsensor, a hydrogen extraction, a hydrogen pressure controller, isotopeenrichment, tritium technology, steam electrolysis, H₂S electrolysis,HCl electrolysis, hydrogenation of hydrocarbon, dehydrogenation, NH₃formation, an electrochemical cell, an electrochromic device, a gassensor or a NO_(x) trap.

The metal composite oxides included in the electrochemical devicesaccording to the present invention plays a role as an oxygen or protonionic conductor. Accordingly, the metal composite oxide can be used forelectrochemical filtration through a porous filter, electrochemicaltreatment of a gas-state efflux or heterogeneous catalysis. The metalcomposite oxides can also be used in a chemical membrane reaction of areactor for controlling oxidation of hydrocarbon or incorporated into anoxygen separation membrane. In addition, the metal composite oxides canbe used as an electrolyte of a fuel cell that uses hydrogen as a fuel.

Further, the present invention provides an ionic conductor, which hasordered metal defects in a lattice structure of perovskite-like2√{square root over (2)}×2√{square root over (2)}×4 super structure.Herein, crystallographic coordinates of the metal defects may be thesame as described above but are not limited thereto.

In the ionic conductor, movement and transfer of ions can be facilitatedby the open space formed in a lattice due to the metal defects. Theionic conductor according to the present invention may include anycompound with no particular limitation, as long as the compoundfacilitates movement of ions due to the aforementioned structuralfeatures. However, the ionic conductor according to the presentpreferably includes the metal composite oxide represented by the aboveFormula 1.

BEST MODE FOR CARRYING OUT THE INVENTION

Reference will now be made in detail to the preferred embodiments of thepresent invention. It is to be understood that the following examplesare illustrative only and the present invention is not limited thereto.

EXAMPLES 1˜7 Preparation of Novel Metal Composite Oxides Example 1

Strontium carbonate (SrCO₃), lanthanum oxide (La₂O₃) and yttrium oxide(Y₂O₃) were weighed and mixed at a metal-based molar ratio of 5:6:0:4.The resultant mixture was heated at a temperature of 1,000° C. for 48hours. The heated mixture was cooled to room temperature and remixed soas to be in a powder state or to form pellets. The powder or pelletswere heated in air at 1,300° C. for 48 hours, and then cooled tocomplete the preparation of compound Sr₅La₆Ta₄O₂₄.

Example 2

Example 1 was repeated to provide compoundSr_(5.5)La_(4.5)Y₁Ta₄O_(23.75), except that strontium carbonate,lanthanum oxide, yttrium oxide and tantalum oxide were used in a molarratio of 5.5:4.5:1:4 instead of 5:6:0:4.

Example 3

Example 1 was repeated to provide compound Sr₆La_(4.5)Y₁Ta₄O_(23.5),except that strontium carbonate, lanthanum oxide, yttrium oxide andtantalum oxide were used in a molar ratio of 6:4:1:4 instead of 5:6:0:4.

Example 4

Example 1 was repeated to provide compound Sr₇La_(1.5)Y_(2.5)Ta₄O₂₃,except that strontium carbonate, lanthanum oxide, yttrium oxide andtantalum oxide were used in a molar ratio of 7:1.5:2.5:4 instead of5:6:0:4.

Example 5

Example 1 was repeated to provide compound Sr₇La₂Y₂Ta₄O₂₃, except thatstrontium carbonate, lanthanum oxide, yttrium oxide and tantalum oxidewere used in a molar ratio of 7:2:2:4 instead of 5:6:0:4.

Example 6

Example 1 was repeated to provide compound Sr₇La₃Y₁Ta₄O₂₃, except thatstrontium carbonate, lanthanum oxide, yttrium oxide and tantalum oxidewere used in a molar ratio of 7:3:1:4 instead of 5:6:0:4.

Example 7

Example 1 was repeated to provide compound Sr₇La_(1.5)Y_(2.5)Ta₄O₂₃,except that strontium carbonate, lanthanum oxide, yttrium oxide andtantalum oxide were used in a molar ratio of 7.5:1.5:2:4 instead of5:6:0:4.

EXPERIMENTAL EXAMPLE 1 Analysis of Chemical Compositions of MetalComposite Oxides (ICP-AES)

The chemical compositions of the metal composite oxides according to thepresent invention were analyzed by ICP-AES (Inductively Coupled PlasmaAtomic Emission Spectroscope).

As a sample, the strontium-lanthanum-yttrium-tantalum-containingcomposite oxide prepared in Example 1 was used. The sample waspulverized, poured into a glass vial, dissolved with concentrated nitricacid and completely decomposed by using hydrogen peroxide. The samplewas diluted to three different volumes and analyzed by a standard methodusing ICP-AES (GDC Integra XMP).

After ICP elemental analysis was performed on the sample, it was shownthat the molar ratio of strontium, lanthanum, yttrium and tantalum is5.00:6.00:0.00:4.00 (±0.02) in the metal composite oxide according toExample 1. The mole number of oxygen was calculated to be 24 based onthe oxidation numbers of the metals and the above molar ratio.Consequently, it was confirmed that thestrontium-lanthanum-yttrium-tantalum-containing oxide according toExample 1 can be represented by Sr₅La₆Ta₄O₂₄. The chemical compositionsof the metal composite oxides according to Examples 2˜7 could beconfirmed in a similar manner.

EXPERIMENTAL EXAMPLE 2 Analysis of Crystal Structures of Metal CompositeOxides

The following analysis was performed to analyze the crystallographicstructures of the metal composite oxides according to the presentinvention.

2-1. Analysis of Crystal Structure Using X-ray Diffraction Pattern(XRDP)

As samples for diffraction analysis, thestrontium-lanthanum-yttrium-containing composite oxides prepared inExamples 1˜7 were used. Each sample was pulverized and filled in asample holder for X-ray powder diffraction. Each sample was scanned byusing Bruker D8-Advance XRD with CuKα₁ (λ=1.5405 Å) radiation at anapplied voltage of 40 kV and an applied current of 50 mA and with a stepsize of 0.02°.

After reviewing each X-ray diffraction pattern (XRDP) obtained from themetal composite oxides according to Examples 1˜7, lattice parameters ofa=11.661±0.5 Å and c=16.577±0.5 Å were obtained from the positions ofthe XRDP peaks. After indexing all peaks and observing the extinctionrule in each diffraction pattern, a space group of I4₁/a was determined(see Table 1 and FIG. 1). In addition, from the XRDPs with all peaksindexed, it was confirmed that each of metal composite oxides accordingto the present invention is in a pure single phase with no impurity.

TABLE 1 Space Examples Composition group Lattice parameters [Å] 1Sr₅La₆Ta₄O₂₄ I4₁/a a = 11.661, c = 16.577 2Sr_(5.5)La_(4.5)Y₁Ta₄O_(23.75) I4₁/a a = 11.672, c = 16.467 3Sr₆La₄Y₁Ta₄O_(23.5) I4₁/a a = 11.694, c = 16.475 4Sr₇La_(1.5)Y_(2.5)Ta₄O₂₃ I4₁/a a = 11.692, c = 16.512 5 Sr₇La₂Y₂Ta₄O₂₃I4₁/a a = 11.669, c = 16.558 6 Sr₇La₃Y₁Ta₄O₂₃ I4₁/a a = 11.729, c =16.463 7 Sr_(7.5)La_(1.5)Y₂Ta₄O_(22.75) I4₁/a a = 11.701, c = 16.571

2-2. Setting of Structural Model and Rietveld Refinement AnalysisResults

To determine the crystal structure of the metal composite oxidesaccording to the present invention, all peaks obtained from ExperimentalExample 2-1 were analyzed by carrying out LeBail fitting with the GSASprogram (A. C. Larson and R. B. Von Dreele, “General Structure AnalysisSystem,” Report no. LAUR086-748, Los Alamos National Laboratory, LosAlamos, N. Mex. 87545), so as to obtain structural factors. Then, themetal composite oxides according to the present invention were subjectedto crystal structure analysis by using the crystal structure solution ofa single crystal based on CRYSTALS (D. J. Watkin, C. K. Prout, J. R.Carruthers, P. W. Betteridge, CRYSTALS, Issue 10; ChemicalCrystallography Laboratory, University of Oxford: Oxford, U.K. 1996).And Rietveld refinement analysis was performed for each XRD pattern bytaking the (x,y,z) coordinates of atoms, site occupancies andtemperature factors as parameters. After the Rietveld analysis, thereliability of the structural model set by the inventors of the presentinvention was R_(w)=6.1%. The final crystallographic data obtained fromthe analysis are shown in the following Table 2.

In addition, it can be seen from FIG. 2 showing a Rietveld profile thatthe pattern measured from the metal composite oxides conforms to thetheoretical pattern of the structural model. In other words, thedifference peaks observed below the Bragg position in the Rietveldprofile indicate that the measured peaks conform to the simulation peaksof the structural model in all measurement sections. This demonstratesthat the crystal structure determination in Table 2 using the structuralmodel is correct, and the metal composite oxides according to thepresent invention are in a single phase.

Particularly, it is to be noted that metal ion defects are in an orderedstate in the crystal structure, wherein the metal ion defect sites havecrystallographic coordinates of position 4a (x=0, y=0.25, z=0.125).

TABLE 2 Atom Site X Y z Occup. Beq Sr1 16f 0.2945 (7)  0.0174 (7) 0.8654 (5)  0.5 1 La1 16f 0.2945 (7)  0.0174 (7)  0.8654 (5)  0.5 1 La216f 0.2078 (6)  0.2250 (7)  0.0352 (4)  1 1 Ta1 8c 0 0   0   1 1 Ta2 8d0 0   0.5 1 1 Sr2 8e 0 0.25 0.3843 (7)  1 1 Sr3 4b 0 0.25  0.625 1 1 O116f 0.936 (7) 0.383 (8) 0.089 (4) 1 1 O2 16f 0.383 (7) 0.374 (6) 0.027(4) 1 1 O3 16f 0.491 (7) 0.951 (6) 0.113 (3) 1 1 O4 16f 0.367 (6) 0.090(5) 0.007 (4) 1 1 O5 16f 0.880 (7) 0.125 (7) 0.968 (4) 1 1 O6 16f 0.102(6) 0.568 (6) 0.077 (4) 1 1 Atomic positions in Sr₅La₆Ta₄O₂₄ with spacegroup No. 88, origin choice 2, and a = 11.661 ± 0.5□, c = 16.577 ± 0.5□.

For reference, FIG. 3 is a crystal lattice structure view ofSr₅La₆Ta₄O₂₄ as shown in Table 2. Herein, TaO₆ molecules are illustratedas dotted octahedrons. Also, La atoms and Sr atoms are illustrated asfilled circles and hatched circles, respectively, in the latticestructure. Additionally, La—O bonding is illustrated as thick lines. Itcan be seen that the octahedrons form an interconnection channel betweeneach other.

EXPERIMENTAL EXAMPLE 3 Evaluation of Oxygen Ionic Conductivity

The following experiment was carried out to evaluate the ionicconductivity of the metal composite oxides prepared according to thepresent invention.

As samples, the strontium-lanthanum-yttrium-containing composite oxidesaccording to Examples 1˜7 were used. Conductivity of each sample wasmeasured according to the DC four-terminal method as a function oftemperature. More particularly, each sample was sintered at a highertemperature than the temperature where the sample was prepared, and thenit was processed into the form of a bar. Then, strip-like porous Ptelectrodes were applied to four positions including both ends and themiddle portion of the sample piece to form electrodes. A voltage dropwas read at the two inner electrodes, while allowing electric current toflow through the two outer electrodes. At this time, electric currentwas applied in such a range that the voltage can be maintained in arange between −1V and 1V. The resistance and conductivity of each samplewere calculated from the voltage and current measured as describedabove. For reference, the total conductivity measured by the two methodsexists within a range of experimental error as compared to the totalconductivity measured in the air and the total conductivity measured innitrogen atmosphere. Therefore, the overall conductivity can be regardedas ionic conductivity.

After the experiment, it can be seen that the metal composite oxideshaving various chemical compositions according to the present inventionexhibit an excellent oxygen ionic conductivity at various temperatures(see FIG. 4). It is thought that such excellent oxygen ionicconductivity of the metal composite oxide according to the presentinvention results from the open space formed within the lattice by themetal ion defects present in the crystal structure. Therefore, the metalcomposite oxide of the present invention can be used as an ionicconductor.

INDUSTRIAL APPLICABILITY

As can be seen from the foregoing, the metal composite oxide accordingto the present invention has an improved ionic conductivity, becauseformation of an open space within a lattice is ensured by the defects ofmetal ion sites in the lattice. Therefore, the metal composite oxide ofthe present invention is useful for an ionic conductor or anelectrochemical device requiring ionic conductivity.

While this invention has been described in connection with what ispresently considered to be the most practical and preferred embodiment,it is to be understood that the invention is not limited to thedisclosed embodiment and the drawings. On the contrary, it is intendedto cover various modifications and variations within the spirit andscope of the appended claims.

1. A metal composite oxide represented by the following Formula 1:[Formula 1]Sr_(5+x+y)La_(6−x−2y)Y_(y)B₄O_(24−δ)C_(z)  (I) wherein B is at least oneelement selected from the group consisting of Ta and Nb; C is at leastone anion selected from the group consisting of S and halogen atoms, orH⁺ cation; x is a decimal ranging from −1 to 1 (−1≦x≦1); y is a decimalranging from 0 to 2.5 (0≦y≦2.5); δ is a decimal ranging from 0 to 3(0≦δ≦3); and z is a decimal ranging from 0 to 7 (0≦z≦7).
 2. The metalcomposite oxide according to claim 1, which includes specific metal iondefects present in an ordered state in a lattice structure.
 3. The metalcomposite oxide according to claim 2, wherein the metal ion defects havecrystallographic coordinates of 4a (x=0, y=0.25, z=0.125).
 4. The metalcomposite oxide according to claim 1, which has a tetragonal crystalsystem.
 5. The metal composite oxide according to claim 1, which belongsto a space group of I4₁/a, whose lattice parameters include:a=11.661±0.5 Å and c=16.577±0.5 Å.
 6. The metal composite oxideaccording to claim 1, which is at least one composite oxide selectedfrom the group consisting of Sr₅La₆Ta₄O₂₄,Sr_(5.5)La_(4.5)Y₁Ta₄O_(23.75), Sr₆La₄Y₁Ta₄O_(23.5),Sr₇La_(1.5)Y_(2.5)Ta₄O₂₃, Sr₇La₂Y₂Ta₄O₂₃, Sr₇La₃Y₁Ta₄O₂₃ andSr_(7.5)La_(1.5)Y₂Ta₄O_(22.75).
 7. An ionic conductor comprising themetal composite oxide as defined in claim 1, wherein the metal compositeoxide represented by the following Formula 1: [Formula 1]Sr_(5+x+y)La_(6−x−2y)Y_(y)B₄O_(24−δ)C_(z)  (I) wherein B is at least oneelement selected from the group consisting of Ta and Nb; C is at leastone anion selected from the group consisting of S and halogen atoms, orH⁺ cation; x is a decimal ranging from −1 to 1 (−1≦x≦1); y is a decimalranging from 0 to 2.5 (0≦y≦2.5); δ is a decimal ranging from 0 to 3(0≦δ≦3); and z is a decimal ranging from 0 to 7 (0≦z≦7).
 8. The ionicconductor according to claim 7, wherein the metal composite oxideincludes specific metal ion defects present in an ordered state in alattice structure.
 9. The ionic conductor according to claim 7, whereinthe metal ion defects have crystallographic coordinates of 4a (x=0,y=0.25, z=0.125).
 10. The ionic conductor according to claim 7, which isoxygen- or proton (H⁺)-selective.
 11. An electrochemical devicecomprising the ionic conductor as defined in claim
 7. 12. Theelectrochemical device according to claim 11, which is selected from thegroup consisting of an oxygen probe, a fuel cell, a chemical membranereactor, an oxygen separation membrane, an oxygen pump, a hydrogenseparation membrane, a hydrogen pump, a hydrogen gas sensor, a steamsensor, a hydrocarbon sensor, a hydrogen extraction, a hydrogen pressurecontroller, isotope enrichment, tritium technology, steam electrolysis,H₂S electrolysis, HCl electrolysis, hydrogenation of hydrocarbon,dehydrogenation, NH₃ formation, an electrochemical cell, anelectrochromic device, a gas sensor, or a NO_(x) trap.